Bolztmann's H-theorem
In his 'H-theorem' Boltzmann tried to formally prove that inter-molecular collisions drive gases toward equilibrium, confirming the Second Law (for gases at least). In this approach, he aimed show that it is not just overwhelmingly probable but an exceptionless law like conservation of energy.
The H-theorem was the first of two approaches to demonstrating the Second Law associated with Boltzmann. The second approach utilized a probabilistic argument and has proven much more durable (it is cross-linked to this map element).
Immediately related elementsHow this works
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The Arrow of Time  »The Arrow of Time 
The physics of time »The physics of time
The thermodynamic arrow »The thermodynamic arrow
Why do we see an entropy gradient? »Why do we see an entropy gradient?
Asymmetric physical processes »Asymmetric physical processes
Bolztmann's H-theorem
Also boundary condition? »Also boundary condition?
Proof of the H-theorem »Proof of the H-theorem
Loschmidt's paradox »Loschmidt's paradox
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